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Molecular Spectroscopy

9 Official GATE PH Questions with Verified Solutions & Answer Keys

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Solved Questions for Molecular Spectroscopy

GATE PH 2007 • Q50 (MCQ) +2 Mark

The number of fundamental vibrational modes of COz molecule is (A) four: 2 are Raman active and 2 are infrared active. (B) four : 1 is Raman active and 3 are infrared active. (C) t...

View Step-by-Step Derivation → • Answer Key: 0
GATE PH 2008 • Q49 (MCQ) +2 Mark

A pure rotational Raman spectrum of a linear diatomic molecule is recorded using electromagnetio radiation of frequency Ve. The frequency of two consecutive Stokes lines are (A) v....

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GATE PH 2009 • Q15 (MCQ) +1 Mark

The separation between the first Stokes and corresponding anti-Stokes lines of the rotational Raman spectrum in terms of the rotational constant, B is (A) 2B (B) 4B (C) 6B (D) 12B...

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GATE PH 2011 • Q43 (MCQ) +2 Mark

The far infrared rotational absorption spectrum of a diatomic molecule shows equidistant lines with spacing 20 cm*' . The position of the first Stokes line in the rotational Raman ...

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GATE PH 2012 • Q16 (MCQ) +1 Mark

The first Stokes line of a rotational Raman spectrum is observed at 12.96 cm-1. Considering the rigid rotor approximation, the rotational constant is given by...

View Step-by-Step Derivation → • Answer Key: C
GATE PH 2018 • Q19 (MCQ) +1 Mark

The expression for the second overtone frequency in the vibrational absorption spectra of a diatomic molecule in terms of the harmonic frequency we and anharmonicity constant Xe is...

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GATE PH 2021 • Q32 (NAT) +1 Mark

The spacing between two consecutive S-branch lines of the rotational Raman spectra of hydrogen gas is 243.2 cm 1. After excitation with a laser of wavelength 514.5 nm, the Stoke's ...

View Step-by-Step Derivation → • Answer Key: 17367 to 17371
GATE PH 2022 • Q32 (NAT) +1 Mark

In a solid, a Raman line observed at 300 cm-1 has intensity of Stokes line four times that of the anti-Stokes line. The temperature of the sample is _______K. (Round off to the nea...

View Step-by-Step Derivation → • Answer Key: 311 to 312
GATE PH 2026 • Q34 (NAT) +1 Mark

Raman spectrum of a molecule was recorded using a source of wavelength 5000 Å. The first Stokes line is observed at 5100 Å. The first anti-Stokes line will appear at a wavelength L...

View Step-by-Step Derivation → • Answer Key: 4901 to 4905