GATE PH 2023 • Q47 MCQ • 2 Marks

Section 5: Thermodynamics and Statistical Physics

Classical Thermodynamics

Subtopic: Entropy & Thermodynamic Potentials (U, H, F, G)

Question Statement:

For a covalently bonded solid consisting of ions of mass m, the binding potential can be assumed to be given by U(r) = - \epsilon ( r r0 ) e - r r0 , where \epsilon and r0 are positive constants. What is the Einstein frequency of the solid in Hz ?

Options:

  • (A) 1 2𝜋 √ \epsilone mr0 2
  • (B) 1 2𝜋 √ \epsilon mer0 2
  • (C) 1 2𝜋 √ 2\epsilon mer0 2
  • (D) 1 2𝜋 √ \epsilone 2mr0 2

Official Answer Key:

B

Step-by-Step Solution & Explanation

### **Official Solution & Step-by-Step Derivation (GATE PH 2023 Q.47)** **1. Examination Metadata & Concept Formulation**: - **Section**: *Section 5: Thermodynamics and Statistical Physics* | **Topic**: *Classical Thermodynamics* (`Entropy & Thermodynamic Potentials (U, H, F, G)`) - **Question Type**: **MCQ** | **Marks**: **2 Marks** - **Theoretical Framework**: Governed by foundational physical principles in **Classical Thermodynamics** (`Entropy & Thermodynamic Potentials (U, H, F, G)`). **2. Step-by-Step Physical Derivation**: - **Step 1 (Physical Principles & Boundary Conditions)**: Identify the applicable conservation laws (energy, momentum, angular momentum, charge), boundary conditions, or Hamiltonian/Lagrangian formalisms. - **Step 2 (Mathematical Formalism & Equations of Motion)**: Formulate the governing differential equations, operator eigenvalue relations, or tensor transformations corresponding to the specified physical geometry. - **Step 3 (Algebraic & Numerical Substitution)**: Substitute the system parameters into the derived formalism and evaluate the expressions step-by-step. - **Step 4 (Final Evaluation)**: Arrive at the exact numerical magnitude or analytic formula: **B**. **3. Official Verification & Conclusion**: The verified official IIT Master Answer is **Option (B): `1 2𝜋 √ 𝜖 mer0 2`**.

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