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Question 36
GATE PH 2022 • Q36
MCQ • 2 Marks
Section 3: Electromagnetic Theory
Electrostatics and Magnetostatics
Subtopic: Biot-Savart Law & Ampere's Circuital Law
Question Statement:
Consider a non-interacting gas of spin 1 particles, each with magnetic moment 𝜇,
placed in a weak magnetic field B, such that
L ≪ 1. The average magnetic
moment of a particle is
Options:
(A) $\frac{2\mu}{3} \left(\frac{\mu B}{k_B T}\right)$
(B) $\frac{\mu}{2} \left(\frac{\mu B}{k_B T}\right)$
(C) $\frac{\mu}{3} \left(\frac{\mu B}{k_B T}\right)$
(D) $\frac{3\mu}{4} \left(\frac{\mu B}{k_B T}\right)$
Step-by-Step Solution & Explanation
### **Official Solution & Step-by-Step Derivation (GATE PH 2022 Q.36)**
**1. Statistical Mechanics Principles (Paramagnetism of Spin 1 Particles)**:
- Magnetic moment of spin-1 particle: $\vec{\mu} = \mu \vec{S}$.
- Under magnetic field $\vec{B} = B\hat{z}$, magnetic quantum number $m_S \in \{-1, 0, +1\}$.
- Zeeman energies:
$E(m_S) = -m_S \mu B \implies E(+1) = -\mu B, \quad E(0) = 0, \quad E(-1) = +\mu B$
**2. Detailed Step-by-Step Derivation**:
- Single-particle partition function:
$Z_1 = \sum_{m_S = -1}^1 e^{-\beta E(m_S)} = e^{\beta \mu B} + 1 + e^{-\beta \mu B} = 1 + 2\cosh(\beta \mu B)$
- For weak magnetic field $\beta \mu B = \frac{\mu B}{k_B T} \ll 1$:
$\cosh(\beta \mu B) \approx 1 + \frac{(\beta \mu B)^2}{2} \implies Z_1 \approx 3$
$\sinh(\beta \mu B) \approx \beta \mu B$
- Average magnetic moment $\langle \mu_z \rangle$:
$\langle \mu_z \rangle = \frac{\mu e^{\beta \mu B} - \mu e^{-\beta \mu B}}{Z_1} = \frac{2\mu \sinh(\beta \mu B)}{1 + 2\cosh(\beta \mu B)}$
- Expanding to first order in $\frac{\mu B}{k_B T}$:
$\langle \mu_z \rangle \approx \frac{2\mu (\beta \mu B)}{3} = \frac{2\mu}{3} \left(\frac{\mu B}{k_B T}\right)$
**3. Official Verification**:
The verified official IIT Master Answer is **Option (A)** (`2\mu / 3 (\mu B / k_B T)`).
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