GATE PH 2022 • Q21 MSQ • 1 Mark

Section 4: Quantum Mechanics

Angular momentum & Hydrogen Atom

Subtopic: Orbital Angular Momentum & Spherical Harmonics

Question Statement:

From the pairs of operators given below, identify the ones which commute. Here l and j correspond to the orbital angular momentum and the total angular momentum, respectively.

Options:

  • (A) l2, j2
  • (B) j2, j
  • (C) j2, l
  • (D) l, j

Official Answer Key:

A, B, D

Step-by-Step Solution & Explanation

### **Official Solution & Step-by-Step Derivation (GATE PH 2022 Q.21)** **1. Quantum Angular Momentum Algebra**: - Orbital angular momentum $\vec{l}$ and total angular momentum $\vec{j} = \vec{l} + \vec{s}$. - Fundamental commutation relations: $[l_i, l_j] = i\hbar \epsilon_{ijk} l_k, \quad [j_i, j_j] = i\hbar \epsilon_{ijk} j_k, \quad [l_i, s_j] = 0$ **2. Step-by-Step Verification of Operator Pairs**: - **Pair (A) $[l^2, j^2]$**: $j^2 = l^2 + s^2 + 2\vec{l}\cdot\vec{s}$ Since $[l^2, l_i] = 0$ and $[l^2, s_i] = 0$, $l^2$ commutes with $\vec{l}\cdot\vec{s}$, so $[l^2, j^2] = 0$. **(A) COMMUTES**. - **Pair (B) $[j^2, j_z]$**: By canonical angular momentum algebra, total magnitude operator $j^2$ commutes with any of its components $j_z$: $[j^2, j_z] = 0$. **(B) COMMUTES**. - **Pair (C) $[j^2, l_z]$**: $[j^2, l_z] = [l^2 + s^2 + 2(l_x s_x + l_y s_y + l_z s_z), l_z]$ Since $[l_x, l_z] = -i\hbar l_y$ and $[l_y, l_z] = i\hbar l_x$, $[j^2, l_z] = 2(-i\hbar l_y s_x + i\hbar l_x s_y) \ne 0$. (C) DOES NOT COMMUTE. - **Pair (D) $[l_z, j_z]$**: $j_z = l_z + s_z \implies [l_z, j_z] = [l_z, l_z + s_z] = [l_z, l_z] + [l_z, s_z] = 0 + 0 = 0$ **(D) COMMUTES**. **3. Official Verification**: The verified official IIT Master Answer is **Options (A, B, D)**.

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