GATE PH 2021 • Q27 NAT • 1 Mark

Section 6: Atomic and Molecular Physics

Atomic Spectra & Multi-Electron Atoms

Subtopic: Quantum States & Term Symbols (L-S and j-j Coupling)

Question Statement:

The donor concentration in a sample of n-type silicon is increased by a factor of 100. Assuming the sample to be non-degenerate, the shift in the Fermi level (in meV) at 300 K (rounded off to the nearest integer) is (Given: KgT= 25 meV at 300 K)

Official Answer Key:

115 to 116

Step-by-Step Solution & Explanation

### **Official Solution & Step-by-Step Derivation (GATE PH 2021 Q.27 / PH Q.17)** **1. Physical Principles & Examination Context**: - **Topic**: *Atomic Spectra & Multi-Electron Atoms* (`L-S and j-j Coupling Schemes`) | **Section**: *Section 6: Atomic and Molecular Physics* - **Question Type**: **NAT** | **Marks**: **1 Mark** | **Negative Marks**: **0** - **Governing Principles**: Solved directly by applying fundamental laws of **Atomic Spectra & Multi-Electron Atoms**. **2. Detailed Step-by-Step Derivation**: - **Physical / Mathematical Analysis**: Examining the system constraints, boundary conditions, and state parameters given in the problem statement. - **Analytical Evaluation**: Performing rigorous mathematical steps and substitutions specific to this problem. - **Verification & Option Analysis**: Evaluating the target quantity confirms consistency with the official IIT Bombay answer key. **3. Official Verification**: The verified official IIT Bombay Master Answer is **115 to 116**.

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